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Organoboranes. V. The Thermal Cyclization of Dialkylboranes. A Convenient Synthesis of 2,4,4-Trimethyl-1,5-pentanediol and Related 1,5-Diols 1

✍ Scribed by Brown, Herbert C.; Murray, Kenneth J.; [ILL], Helmut; Zweifel, George


Book ID
120487117
Publisher
American Chemical Society
Year
1966
Tongue
English
Weight
647 KB
Volume
88
Category
Article
ISSN
0002-7863

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## Abstract 1,1,1‐Trifluoroalkane‐2,3‐dione 3‐oximes 1 easily obtainable from aldehyde dimethylhydrazones were reacted with several aldehydes and ketones in the presence of acetic acid to afford 4‐trifluoromethyl‐4__H__‐[1,5,2]dioxadines 3 in satisfactory yields. When the reaction was carried out i