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Organoaluminium induced ring-opening of epoxypyranosides. V. Formal total synthesis of antimycin A3 and synthesis of (+)-blastmycinone.

✍ Scribed by Tord Inghardt; Torbjörn Frejd

Publisher
Elsevier Science
Year
1991
Tongue
French
Weight
752 KB
Volume
47
Category
Article
ISSN
0040-4020

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Organoaluminium induced ring-opening of
Organoaluminium induced ring-opening of epoxypyranosides. IV. Synthesis and structure of γ- hydroxy-lsoleucine stereoisomers and their corresponding lactones.
✍ Tord Inghardt; Torbjörn Frejd; Göran Svensson 📂 Article 📅 1991 🏛 Elsevier Science 🌐 French ⚖ 919 KB

Key Wordy: tnmethylaluminium; opening of epoxide and pymnoside rings; 2.3~anhydr+L-ribopyranosik y-hydroxy-i&wine; x-ray data. ## Abstmct: Two r hydroxy-isoleucine stereoisomers 8 (2R. 3R, 4R), and 14 (2s. 3R, 4R) as well as their corresponding y lactones 9 and IS were synthesised using a tandem,