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Organic synthesis by electrolysis III anodic allylic substitution

✍ Scribed by Tatsuya Shono; Tōru Kōsaka

Book ID
104212489
Publisher
Elsevier Science
Year
1968
Tongue
French
Weight
92 KB
Volume
9
Category
Article
ISSN
0040-4039

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The first copper-catalyzed allylic substitution reactions of allylic acetates and carbamates employing a bis(triorganosilyl)zinc reagent are reported. This novel procedure avoids the use of stoichiometric amounts of copper salts which are usually mandatory with this chemistry. Application of this me