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Organic synthesis by electrolysis IV Electrolytic generation of sulfonium ylide

✍ Scribed by Tatsuya Shono; Michiharu Mitani


Publisher
Elsevier Science
Year
1969
Tongue
French
Weight
157 KB
Volume
10
Category
Article
ISSN
0040-4039

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A novel synthesis of 2,3-dihydro-1H-thie
✍ Hiroshi Maruoka; Kenji Yamagata; Fumi Okabe; Yukihiko Tomioka πŸ“‚ Article πŸ“… 2005 πŸ› Journal of Heterocyclic Chemistry 🌐 English βš– 89 KB

A series of cyclic sulfonium ylides 4a-h reacted with titanium(IV) chloride in the presence of triethylamine to give the corresponding fused 2,3-dihydro-1H-thieno [3,4-b]pyrroles 5a-h, via a ring opening and recyclization. In contrast, treatment of compounds 4a, 4b, 4e and 4f with titanium(IV) chlor