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Organic reactions in liquid hydrogen fluoride. III. Carboxylic acids from olefins and carbon monoxide (hydrogen fluoride-Koch reaction)

✍ Scribed by Norell, John R.


Book ID
126100929
Publisher
American Chemical Society
Year
1972
Tongue
English
Weight
667 KB
Volume
37
Category
Article
ISSN
0022-3263

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## Abstract Anchimerically assisted rearrangement, observed in the fluorination of some α‐amino acids with 70 : 30 (w/w) hydrogen fluoride/pyridine (by weight) in the presence of NaNO~2~, is substantially or fully suppressed by using the less acidic reagent 48 : 52 (w/w) hydrogen fluoride/pyridine.