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Organic reactions at high pressure. The preparative scale synthesis of cantharidin

✍ Scribed by Dauben, William G.; Gerdes, John M.; Smith, David B.


Book ID
121007842
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
432 KB
Volume
50
Category
Article
ISSN
0022-3263

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Organic Reactions at High Pressure: Cycl
✍ Prof. Dr. Frank-Gerrit KlΓ€rner; Dr. Barbara M. J. Dogan; Richard Weider; Prof. D πŸ“‚ Article πŸ“… 1986 πŸ› John Wiley and Sons 🌐 English βš– 393 KB πŸ‘ 1 views

The (R,S)-aminal 3 , prepared from glycine methyl ester hydrochloride, methylamine, and pivalaldehyde,l'"l was treated with 14 chiral carboxylic or sulfonic acids. In two cases one of the two possible diastereomeric salts crystallized selectively: the salt from ( -)-2,3 :4,6-di-O-isopropylidene-2-ke