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Ordering in aqueous polysaccharide solutions. II. Optical rotation and heat capacity of aqueous solutions of a triple-helical polysaccharide schizophyllan

✍ Scribed by Kazuto Yoshiba; Tetsurou Ishino; Akio Teramoto; Naotake Nakamura; Yuji Miyazaki; Michio Sorai; Qi Wang; Yoshihito Hayashi; Naoki Shinyashiki; Shin Yagihara


Publisher
Wiley (John Wiley & Sons)
Year
2002
Tongue
English
Weight
220 KB
Volume
63
Category
Article
ISSN
0006-3525

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Solvent effects on the cooperative order
✍ Takayuki Hirao; Takahiro Sato; Akio Teramoto; Takasuke Matsuo; Hiroshi Suga 📂 Article 📅 1990 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 623 KB

A triple-helical polysaccharide schizophyllan in aqueous solution exhibited a highly cooperative transition between ordered and disordered states associated with the conformation of its side chains and nearby water molecules. The transition was followed by optical rotation and calorimetry using wate