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Dielectric study of the cooperative order–disorder transition in aqueous solutions of schizophyllan, a triple-helical polysaccharide

✍ Scribed by Akio Teramoto; Hong Gu; Yuji Miyazaki; Michio Sorai; Satoru Mashimo


Publisher
Wiley (John Wiley & Sons)
Year
1995
Tongue
English
Weight
552 KB
Volume
36
Category
Article
ISSN
0006-3525

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Solvent effects on the cooperative order
✍ Takayuki Hirao; Takahiro Sato; Akio Teramoto; Takasuke Matsuo; Hiroshi Suga 📂 Article 📅 1990 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 623 KB

A triple-helical polysaccharide schizophyllan in aqueous solution exhibited a highly cooperative transition between ordered and disordered states associated with the conformation of its side chains and nearby water molecules. The transition was followed by optical rotation and calorimetry using wate