Orbital following and hyperconjugation in borane adducts
✍ Scribed by Purcell, Keith F.
- Book ID
- 126397297
- Publisher
- American Chemical Society
- Year
- 1972
- Tongue
- English
- Weight
- 245 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0020-1669
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## Abstract Herein we report on the synthesis and characterization of the adduct 1,1,3,3‐tetramethylguanidine–borane, H~3~B·N(H)C(NMe~2~)~2~, and a general inspection of the bonding properties of guanidine adducts to BH~3~. The new compound was characterized by its vibrational, NMR and mass spectra
## Abstract The 1:1 phenylhydrazine–borane adduct, obtained from phenylhydrazine and sodium borohydride in acidic solution, was investigated by IR, NMR spectroscopy, and MS spectrometry. Ab initio MO calculations indicated the isomer in which the boron center is attached to the primary amino group