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Optimizing the synthesis of 5,10-disubstituted tripyrromethanes

✍ Scribed by Jae-Won Ka; Chang-Hee Lee


Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
143 KB
Volume
41
Category
Article
ISSN
0040-4039

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✦ Synopsis


Condensation of aldehydes with pyrrole in the presence of acid catalyst gave the mixture of dipyrromethanes and tripyrromethanes. The major product was switched from dipyrromethanes to tripyrromethanes according to the sequence of adding the reactants and catalyst. Higher oligomers such as tetrapyrromethane and pentapyrromethane were isolated and characterized from the reaction of 4-methoxycarbonylbenzaldehyde with pyrrole.


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