## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
Optimizing the synthesis of 5,10-disubstituted tripyrromethanes
β Scribed by Jae-Won Ka; Chang-Hee Lee
- Publisher
- Elsevier Science
- Year
- 2000
- Tongue
- French
- Weight
- 143 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
Condensation of aldehydes with pyrrole in the presence of acid catalyst gave the mixture of dipyrromethanes and tripyrromethanes. The major product was switched from dipyrromethanes to tripyrromethanes according to the sequence of adding the reactants and catalyst. Higher oligomers such as tetrapyrromethane and pentapyrromethane were isolated and characterized from the reaction of 4-methoxycarbonylbenzaldehyde with pyrrole.
π SIMILAR VOLUMES
The dianion derived from the oxime of furfuraldehyde (1) reacts with electrophiles at the 5-position of the furan ring; subsequent hydrol$is of the oxime provides a useful method for the synthesis of 2,5\_disubstituted furans.
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v