Optimization of magnetization transfer experiments for kinetic rate measurements
β Scribed by Haim Taitelbaum; George H. Weiss; Richard G. S. Spencer
- Publisher
- John Wiley and Sons
- Year
- 1994
- Tongue
- English
- Weight
- 536 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0952-3480
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π SIMILAR VOLUMES
A recent analysis of the optimization of magnetization transfer experiments to estimate first-order rate constants is extended to the design of experiments for measuring these constants and T , when both parameters are initially unknown. When the number of measurement times is fixed, an optimal desi
## Abstract Accurate rules have been established to build binomial pulses up to fifth order, for selectively saturating protons at any given __T__~2~ with minimum power deposition. Pulse performance and sensitivity to experimental defects have been evaluated; the third order is generally found to b
## Abstract A systematic study was performed to optimize the accuracy of kinetic parameters derived from magnetization transfer measurements. Three techniques were investigated: timeβdependent saturation transfer (TDST), saturation recovery (SRS), and inversion recovery (IRS). In the last two metho