## Abstract The in situ characterization of membranes for fuel cell applications is a rather complex and time‐consuming procedure. It is therefore interesting to develop simple, short, and reproducible characterization tests and to limit in situ measurement only to the most promising materials. In
Optimization of etching parameters of a fluorinated polyimide using the RIBE technique
✍ Scribed by Lucas, Bruno; Moussant, Cyril; Moliton, André; Zyss, Joseph
- Publisher
- John Wiley and Sons
- Year
- 1998
- Tongue
- English
- Weight
- 196 KB
- Volume
- 47
- Category
- Article
- ISSN
- 0959-8103
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✦ Synopsis
A parametric study of etching a new type of Ñuorinated polyimide (6FDA-ODA) has been carried out. This kind of material was especially elaborated for plasma etching (reactive ion etching, RIE) ; its behaviour was tested with the reactive ion beam etching (RIBE) technique which uses an (O) reactive ion beam and allows independent control of the ion energy and current density of the beam. Etch rates were measured as a function of energy (E), current density (J) and incident angle (h) of the beam with the sample normal. These rates were shown to present a maximum value for an energy Ñux (1000 Ó min~1) of about 3 W cm~2 (E \ 6 keV and J \ 0É5 mA cm~2) and decreased when h increased. These results were then compared with etching rates obtained with chemically inert ions (Ar) : in this case, etching rates were Ðve times lower than those measured with O`ions.
Society of Chemical Industry
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