Optimisation of Palladium-Based Supported Liquid-Phase Catalysts in the Heck Reaction
β Scribed by Mirza, Amin R.; Anson, Michael S.; Hellgardt, Klaus; Leese, Matthew P.; Thompson, David F.; Tonks, Louise; Williams, Jonathan M. J.
- Book ID
- 126334511
- Publisher
- American Chemical Society
- Year
- 1998
- Tongue
- English
- Weight
- 82 KB
- Volume
- 2
- Category
- Article
- ISSN
- 1083-6160
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π SIMILAR VOLUMES
The Heck reaction of iodobenzene and 4-methyl-iodobenzene with olefins using silica-supported palladium complex catalysts was conducted in 1-butyl-3-methylimidazolium hexafluorophosphate ([bmim]PF 6 ), exhibiting higher activities than in DMF in addition to easy product isolation and catalyst recycl
## Abstract A polymerβsupported macrocyclic Schiff base palladium complex has been synthesized. In the Heck reaction of aryl iodides and bromides with ethyl acrylate or styrene, the complex has been proved to give the corresponding products in good to excellent yields. The reaction proceeded smooth