A locally optimized theory' was applied to a laser control of a two-dimensional unimolecular rcaction of a triatomic molecule. This molecule is characterized by dissociation and isomeritation channels. The isomeri:,ation is shown to be a dominant reaction by applying a sequence of pulses. To scc ho~
โฆ LIBER โฆ
Optimal control of bond selectivity in unimolecular reactions
โ Scribed by Shenghua Shi; Herschel Rabitz
- Book ID
- 107745488
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- English
- Weight
- 953 KB
- Volume
- 63
- Category
- Article
- ISSN
- 0010-4655
No coin nor oath required. For personal study only.
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Control of IBr photodissociation branching ratios is explored using optimal control theory to design the requisite pulses which produce ground or spin-orbit excited bromine atoms. To conform to experimental pulse shaping limitations, these pulses are confined to a limited bandwidth and further modif