Optically detected magnetic resonance of triplet cyclopentanone. Aggregation and intermolecular exchange in the solid state
โ Scribed by Lynch, W. Bryan; Pratt, David W.
- Book ID
- 111873365
- Publisher
- American Chemical Society
- Year
- 1985
- Tongue
- English
- Weight
- 392 KB
- Volume
- 89
- Category
- Article
- ISSN
- 0022-3654
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๐ SIMILAR VOLUMES
Optically detected magnetic resonance (ODMR) techniques are used to determine the orbital asQnment of the phosphorescent triplet state of p-benzoquinone in the condensed phase. The principal spin-orbit coupl% routes are discussed in terms of the observed spin-vibronic activity.
By magnetic resonance es~criments on the phosphorescing triplet state of biacetyl in a 3-methytpentane glass the zero field splittings and the populating and depopulating rates of the individual triplet spin Ieveis have been me=ured. From these data an assignment of the zero field levels and mechani