Optically detected magnetic resonance of the luminescent state in NaF:Cu+
β Scribed by J. van Tol; J.H. van der Waals
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 774 KB
- Volume
- 194
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
β¦ Synopsis
Optically detected electron paramagnetic resonance (OD-EPR) spectra at 22.9,75.0, and 94.9 GHz of the luminescent state of Cu+ ions in NaF are reported. The EPR spectra do not support the current T,,('E,, 3d94s) "atomic" assignment of the luminescent state, but point to a paramagnetic species with g values in the range of 2.0-2.5, a very small or no zero-field splitting and a spin density in the Cu 4s orbital lower than 0.04.
π SIMILAR VOLUMES
By magnetic resonance es~criments on the phosphorescing triplet state of biacetyl in a 3-methytpentane glass the zero field splittings and the populating and depopulating rates of the individual triplet spin Ieveis have been me=ured. From these data an assignment of the zero field levels and mechani
Optically detected magnetic resonance (ODMR) techniques are used to determine the orbital asQnment of the phosphorescent triplet state of p-benzoquinone in the condensed phase. The principal spin-orbit coupl% routes are discussed in terms of the observed spin-vibronic activity.
Nuclear quadrupole effects on the tnplet-state opircally detected magnetic resonance (ODMR) of molecules having spin I = 1 nuclei have been investigated by theoreucal melhods Beginning W&I an exact dlagonaluanon of the tnpler-state spin Harrultoman, rhese methods have mvolved a systemauc vanallon m