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Optically active ZnII and PtII complexes of the 3-carene type α-amino oxime

✍ Scribed by Alexey V. Tkachev; Pavel A. Petukhov; Sergey N. Konchenko; Sergey V. Korenev; Martin A. Fedotov; Yuri V. Gatilov; Tatyana V. Rybalova; Oksana A. Kholdeeva


Book ID
108036185
Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
416 KB
Volume
6
Category
Article
ISSN
0957-4166

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A series of acyclic and cyclic enol derivatives 1 has been transformed into the corresponding α-amino-functionalized ketones 2 by means of enantioselective catalytic aziridination with chiral Cu complexes, prepared in situ from [Cu(MeCN)4]PF 6 and the optically active ligands 3, by using (N-tosylimi