Optically active transition-metal compounds: XXII. Stereochemistry and crystal structure determination of (η5-C5H5)CoI(NC4H3C(R)=N(S)-CH(CH3)(C6H5)) (R = H, CH3)
✍ Scribed by Ivan Bernal; George M. Reisner; Henri Brunner; Georg Riepl
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 907 KB
- Volume
- 284
- Category
- Article
- ISSN
- 0022-328X
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SUNl4ARY reported. (Co(C0) I (C~HS)ZP-N(CHI) ICH(CH3) (Cdi,)] 1 2 are compared. Synthesis and molecular structure determination of the title compound are The W R spectra of (M~'I~(CO)\*(C~HS)IP-N(CHI) ICH(CH3) (C6Ha)I )Z and CRYSTAL STRUCTURE The crystals are monoclinic with ( I = 11.713(6), b -19.5
The crystallographic dataC3] and the molecular dimensions of ( 4 ) and ( ) are almost identical. We thus have one of those rare cases in which analyses and spectraL4] are more significant in identifying the compounds than structure determination. The most important structural characteristic of ( 4 )