We report the photoluminescence spectrum of well characterized, epitaxially grown single crystal Cm thin films. The highly regular and reproducible spectral features observed can be explained by a simple molecular model which takes into account enhanced coupling of an excited Cm molecule with its ne
Optical studies of single-crystal C60
โ Scribed by P.N. Saeta; B.I. Greene; A.R. Kortan; N. Kopylov; F.A. Thiel
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 184 KB
- Volume
- 190
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
We report optical reflectivity data for single crystals of C60 in the energy range 1.8-4.8 eV. A Kramers-Kronig analysis of the reflectivity spectrum yields an absorption spectrum similar to that of thin films of polycrystalline C6o. Based on the general features of the linear absorption spectrum, it would appear unlikely that crystalline C60 manifests exceptionally large second-or third-order optical nonlinearities.
๐ SIMILAR VOLUMES
Raman spectra (using 5 14 and 740 nm excitation) of high-purity single crystal CbO are presented for the high-and low-temperature phases, showing activity of all "gerade" modes. Within the experimental accuracy, the spectra are found to be consistent with the selection rules for Raman scattering in
FT IR transmission spectra of large single crystals of the clathrates C60" 4C6H6, C6o" xCCI4 where 0.1 < x < 0.2, C6o' C2HCI3 and C60" 1.5CS2 are presented and discussed. Most of the weak lines are identified with activated silent or second-order combination modes of the C60 molecule. It is shown th