Optical spectroscopy of U3+ doped KPb2Cl5 laser crystal
✍ Scribed by Marcin Sobczyk; Janusz Drożdżyński; Radosław Lisiecki; Witold Ryba-Romanowski
- Publisher
- Elsevier Science
- Year
- 2007
- Tongue
- English
- Weight
- 278 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0925-3467
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✦ Synopsis
Non hygroscopic U 3+ :KPb 2 Cl 5 single crystals with a 0.1 mol% U 3+ nominal concentration and good optical quality have been obtained by the Bridgman-Stockbarger method. High-resolution absorption and emission spectra of the crystals were recorded at room temperature in the 4000-25 000 cm À1 and 4000-14 000 cm À1 spectral ranges, respectively. Excitation in the spectral region of 5f 3 ! 5f 2 6d 1 transitions produced a strong near infrared emission from the 4 F 3/2 and 4 I 11/2 energy levels. A Judd-Ofelt intensity analysis has been performed in order to describe the electric dipole strengths of the observed transitions. The obtained phenomenological parameters were used to predict luminescence properties of U 3+ ions doped in the KPb 2 Cl 5 single crystal.
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