We present a simple model for calculating the second-order optical response of a film of chiral molecules. The difference in the output signal for right or left circularly polarized input is analyzed. A strong enhancement in the normalized differential signal is found for p-polarized output. This is
β¦ LIBER β¦
Optical second-harmonic generation from oligothiophene films
β Scribed by F. Geiger; G. Marowsky
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 360 KB
- Volume
- 254
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
We have studied surface second-harmonic generation from thin layers of several oligothiophenes deposited by vacuum sublimation on fused silica substrates, Although these oligothiophenes have a symmetric "rr-electron system, they show a second-harmonic response which is strongly dependent on the conjugation length. Their average orientation was also determined by analyzing the polarization dependence of the second-harmonic signal.
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