We have observed fairly strong second-harmonic generation (SHG) in vacuum-deposited thin films of phthalocyanines (Pc) having central metal atoms; Co, Cu, Zn, VO, TiO, Pb, Sn and a metal-free Pc. Based on the remarkable spectral dependences, the SHG was concluded to be due to higher-order mechanisms
Optical Second Harmonic Generation from a Thin Chiral Film
✍ Scribed by Brudny, V. L. ;Mochán, W. L.
- Publisher
- John Wiley and Sons
- Year
- 1999
- Tongue
- English
- Weight
- 175 KB
- Volume
- 175
- Category
- Article
- ISSN
- 0031-8965
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✦ Synopsis
We present a simple model for calculating the second-order optical response of a film of chiral molecules. The difference in the output signal for right or left circularly polarized input is analyzed. A strong enhancement in the normalized differential signal is found for p-polarized output. This is due to the existence of Brewster angles which are slightly different for R or L circular input. This feature has no analog in the linear signal, since in that case the two Brewster angles coincide.
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