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Optical Rotatory Dispersion Studies. LIX. 1 The Octant Rule and Deuterium. Synthesis of 3-Deuteriocyclopentanone 2

✍ Scribed by Djerassi, Carl; Tursch, B.


Book ID
127212897
Publisher
American Chemical Society
Year
1961
Tongue
English
Weight
545 KB
Volume
83
Category
Article
ISSN
0002-7863

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πŸ“œ SIMILAR VOLUMES


Optical rotatory dispersion studies CXX.
✍ Jan William Simek; Daniell L. Mattern; Carl Djerassi πŸ“‚ Article πŸ“… 1975 πŸ› Elsevier Science 🌐 French βš– 229 KB

Although numerous examples of asymmetric molecules which owe their chirality to isotopic substitution are known, 3 few are reported3 to display Cotton effects in either optical rotatory disper sion(ord) or circular dichroism(cd). We wish to report the successful

Optical rotatory dispersion studies CXI.
✍ W.Scott Briggs; Milos Ε uchΓ½; Carl Djerassi πŸ“‚ Article πŸ“… 1968 πŸ› Elsevier Science 🌐 French βš– 234 KB

The original tenets of the octant rule (1) state that equatorial substituents adjacent tu t+~e ta-r~onyl group in an optically ac-tive cyciohexanone make no sign'ificant conrribution