Asymmetric disturbance by deuterium of intrinsically symmetric chromophores such as the car-bony1 group promises to become a fruitful field for theoretical studies of the octant rule. 2 The first example was (3R)-deuteriocyclopentanone (A), prepared3 by multi-step transformation from (t)-
Optical rotatory dispersion studies CXX. Synthesis and circular dichroism of chiral 3-deuteriocyclopentanone
โ Scribed by Jan William Simek; Daniell L. Mattern; Carl Djerassi
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- French
- Weight
- 229 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
โฆ Synopsis
Although numerous examples of asymmetric molecules which owe their chirality to isotopic substitution are known, 3 few are reported3 to display Cotton effects in either optical rotatory disper sion(ord) or circular dichroism(cd).
We wish to report the successful
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