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Optical resolution of tris(pentane-2,4-dionate) complexes of transition-metal ions

โœ Scribed by Mason, Stephen F.; Peacock, Robert D.; Prosperi, Tomaso

Book ID
125806635
Publisher
The Royal Society of Chemistry
Year
1977
Tongue
English
Weight
372 KB
Volume
7
Category
Article
ISSN
1472-7773

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The twisting power of some chiral tris-(
The twisting power of some chiral tris-(pentane-2,4-dionato)metal(III) complexes in nematic liquid crystals
โœ Alex F. Drake; Giovanni Gottarelli; Gian P. Spada ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 269 KB

The twisting power (0) of tris(pcntane-?,Cdionato)mctal(IlI) complcses was measured in different ncmatic liquid crystals at variable temperature. The results ilie discussed in the li;;ht of current theories of cholcsteric induction. A model is proposed to cxpbin the high values of p observed.