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Emission photoselection studies of transition-metal complexes. 2. Tris(diimine) complexes

✍ Scribed by DeArmond, M. Keith; Carlin, Clifford M.; Huang, Wen Liang

Book ID
126311388
Publisher
American Chemical Society
Year
1980
Tongue
English
Weight
825 KB
Volume
19
Category
Article
ISSN
0020-1669

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Two mixed-ligand complexes, cis-[Ir(bipy)(HDPA)Cl 2 ]Cl and cis-[Ir(phen)(HDPA)Cl 2 ]Cl (where bipy = 2,2%-bipyridine, phen = 1,10-phenanthroline, and HDPA =2,2%-dipyridylamine), have been synthesized and characterized. Both complexes show spin-allowed p -p\* bands in the UV region. Besides, spin-al