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Optical Resolution of a 1,2,5,6-Dibenzcycloöctatetraene Derivative

✍ Scribed by Mislow, Kurt.; Perlmutter, Howard D.


Book ID
124165421
Publisher
American Chemical Society
Year
1962
Tongue
English
Weight
268 KB
Volume
84
Category
Article
ISSN
0002-7863

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The cyclopolymerization of 3,4-di-O-allyl-1,2 : 5,6-dianhydro-D-mannitol ( 1) was carried out using BF 3 rOEt 2 and t-BuOK. The polymer obtained by the polymerization with BF 3 rOEt 2 mainly consisted of (1r6)-bonded 3,4-di-O-allyl-2,5-anhydro-Dglucitol as the five-membered constitutional repeating