Optical properties of sugars. 3. Circular dichroism of aldo- and ketopyranose anomers
โ Scribed by Nelson, Richard G.; Johnson, W. Curtis
- Book ID
- 126210454
- Publisher
- American Chemical Society
- Year
- 1976
- Tongue
- English
- Weight
- 681 KB
- Volume
- 98
- Category
- Article
- ISSN
- 0002-7863
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## Abstract The CD spectra of amylose, the maltose oligomers, cellobiose, and the cyclodextrins are measured in aqueous solution to 1640 ร . Two bands are found in this region. An examination of chromophorically equivalent but conformationally different glucans demonstrates that the CD of glucans is
Although numerous examples of asymmetric molecules which owe their chirality to isotopic substitution are known, 3 few are reported3 to display Cotton effects in either optical rotatory disper sion(ord) or circular dichroism(cd). We wish to report the successful