The inelastic depolarized light-scattering spectrum of the endohedral metallofullerene Li+@& is calculated for frequency shifts up to 1000 cm-'. In this species the motion of the charged inclusion within the buckyball cage generates an induced anisotropic polarisability through an interesting mechan
Optical properties of endohedral Li@C60
β Scribed by A. Gromov; N. Krawez; A. Lassesson; D.I. Ostrovskii; E.E.B. Campbell
- Publisher
- Elsevier Science
- Year
- 2002
- Tongue
- English
- Weight
- 156 KB
- Volume
- 2
- Category
- Article
- ISSN
- 1567-1739
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Endohedral N@C, (atomic nitrogen inside C,) is produced by ion implantation. N@C, is soluble in organic solvents and stable in air. A special feature is that it gives a very clear hyperiine split EPR signal with sharp lines even in the solid. This makes it an ideal probe for monitoring chemical reac
The character of the bond between encapsulated atoms and the enclosing C6o shell in M@C6o endohedral complexes is revisited using the density functional formalism. Mulliken population analysis indicates that this bond is strongly ionic in the case of K@C6o , predominantly covalent in the case of O@C