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Optical detection of endor in a zero-field transition of phosphorescent quinoxaline

โœ Scribed by I.Y. Chan; J. Schmidt; J.H. van der Walls


Book ID
107731339
Publisher
Elsevier Science
Year
1969
Tongue
English
Weight
542 KB
Volume
4
Category
Article
ISSN
0009-2614

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๐Ÿ“œ SIMILAR VOLUMES


Optical detection of zero-field transiti
โœ J. Schmidt; J.H. Van Der Waals ๐Ÿ“‚ Article ๐Ÿ“… 1968 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 307 KB

Recently several investigators reported opti-aZ detection of ESR transitions in phosphoresent triplet states of various molecules [l-3]. he experiments were done by sweeping the magetic field at fixed microwave frequency. In con-;ast with the normal ESR detection method. the Jsorption of microwave p

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The ENDOR spectrum of the high-frequency ESR transition of phosphorescent quinoline in zero field is in vestigated. The findings are in accord with a recent analysis of Buckley et al. From the observed ENDOR ftequencics the quadrupolar splitting of the 14N nucleus in the phosphorescent state is dete

Optical detection of the zero field spli
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The zero fickl transition energies in the phosphorwcent triplet state of neat SO 2 arc discctly mctsurcd by opticlL detedtion at 1.4"K, leading to LDI = 0.275 cm-' and LEI = 0.01575 cm-' for the usual spin hamiltonian parameters. Two spin states are found to be active in the phosphorescence with th