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Optical activity. Empirical correlation between optical rotation and bond refraction

✍ Scribed by Davis, Dennis Duval.; Jensen, Frederick R.

Book ID
127139615
Publisher
American Chemical Society
Year
1970
Tongue
English
Weight
857 KB
Volume
35
Category
Article
ISSN
0022-3263

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Correlation between optical rotation sign and conformation of γ-butyrolactones. An empirical correlation rule to predict optical activity and stereochemistry of γ-butyrolactones
✍ Fu-An Kang; Cheng-Lie Yin 📂 Article 📅 1998 🏛 Elsevier Science 🌐 French ⚖ 602 KB

A series of trans-4,5-disubstituted-y-buty~iactones are found to adopt different conformations by aH NMR spectroscopy, whose optical rotation signs are found to depend on the conformations they assume. An empirical correlation rule is proposed for the prediction of optical activity and stereochemist