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An empirical correlation between structure and optical activity in a series of labdane diterpenoids

โœ Scribed by V. A. Raldugin


Book ID
112379864
Publisher
Springer
Year
1981
Tongue
English
Weight
384 KB
Volume
17
Category
Article
ISSN
0009-3130

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โœ Fu-An Kang; Cheng-Lie Yin ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 602 KB

A series of trans-4,5-disubstituted-y-buty~iactones are found to adopt different conformations by aH NMR spectroscopy, whose optical rotation signs are found to depend on the conformations they assume. An empirical correlation rule is proposed for the prediction of optical activity and stereochemist