Synthesis of a Chiral Palladacycle and I
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Yi Ding; Yi Zhang; Yongxin Li; Sumod A. Pullarkat; Paul Andrews; Pak-Hing Leung
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Article
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2010
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John Wiley and Sons
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English
⚖ 465 KB
👁 2 views
## Abstract A novel amine ligand, 1‐(2,5‐dimethylphenyl)‐__N__,__N__,2,2‐tetramethylpropan‐1‐amine, was synthesized in six steps from commercially available __p__‐xylene. Direct __ortho__‐palladation of this amine ligand proceeded readily to form the racemic dimeric complex. The palladacycle struct