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One-step synthesis of a thioester chiral PMO and its use as a catalyst in asymmetric oxidation reactions

✍ Scribed by García, Rafael A. ;Morales, Victoria ;Garcés, Teresa


Book ID
125793494
Publisher
Royal Society of Chemistry
Year
2012
Tongue
English
Weight
758 KB
Volume
22
Category
Article
ISSN
0959-9428

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## Abstract A novel amine ligand, 1‐(2,5‐dimethylphenyl)‐__N__,__N__,2,2‐tetramethylpropan‐1‐amine, was synthesized in six steps from commercially available __p__‐xylene. Direct __ortho__‐palladation of this amine ligand proceeded readily to form the racemic dimeric complex. The palladacycle struct