One-step in situ ball milling synthesis of polymer-functionalized graphene nanocomposites
✍ Scribed by Wu, Hang; Zhao, Weifeng; Hu, Huawen; Chen, Guohua
- Book ID
- 111949886
- Publisher
- Royal Society of Chemistry
- Year
- 2011
- Tongue
- English
- Weight
- 479 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0959-9428
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Graphene oxide (GO) is reduced and functionalized with primary amine by a one-pot solvothermal process using ethylene glycol as solvent and ammonia water as nitrogen precursor at 180 °C for 10 h. The reaction is featured by nucleophilic substitution of -COOH and C-O-C groups by the ammonia radicals.
## Abstract Propargyl acrylate‐based functionalizable monolithic stationary phase (FMSP) for capillary electrochromatography, easily modifiable by alkyne–azide 1,3‐dipolar cycloaddition, is developed. Optimization of FMSP is focused on (i) physical properties: rigidity, stability, and pore size and