One-step conversions of a simple corrole into chiral and amphiphilic derivatives
β Scribed by Irena Saltsman; Israel Goldberg; Zeev Gross
- Publisher
- Elsevier Science
- Year
- 2003
- Tongue
- French
- Weight
- 160 KB
- Volume
- 44
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
The reactions of phosgene with 5,10,15-tris(pentafluorophenyl)corrole and its gallium(III) complex lead to a novel chiral macrocycle and an amphiphilic corrole, respectively. Both types of molecules were fully characterized by spectroscopy and X-ray crystallography.
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