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A one-step conversion of isoquinolinium salts into naphthalene derivatives

✍ Scribed by M. Shamma; L.A. Smeltz; J.L. Moniot; L. Tőke

Publisher
Elsevier Science
Year
1975
Tongue
French
Weight
188 KB
Volume
16
Category
Article
ISSN
0040-4039

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✦ Synopsis

Isoqulnolinium salts *re known to undergo ring opening when strong electron withdrawing groups are directly bonded to the nitrogen atom. 3a-d We now wish to report a new and unusual ring opening of alkyl isoquinolinlum salts. Treatment of such salts with sodium

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✍ Irena Saltsman; Israel Goldberg; Zeev Gross 📂 Article 📅 2003 🏛 Elsevier Science 🌐 French ⚖ 160 KB

The reactions of phosgene with 5,10,15-tris(pentafluorophenyl)corrole and its gallium(III) complex lead to a novel chiral macrocycle and an amphiphilic corrole, respectively. Both types of molecules were fully characterized by spectroscopy and X-ray crystallography.