One-Step Biocatalytic Synthesis of Linear Polyesters with Pendant Hydroxyl Groups
โ Scribed by Kline, Billie J.; Beckman, Eric J.; Russell, Alan J.
- Book ID
- 118740749
- Publisher
- American Chemical Society
- Year
- 1998
- Tongue
- English
- Weight
- 126 KB
- Volume
- 120
- Category
- Article
- ISSN
- 0002-7863
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๐ SIMILAR VOLUMES
Oligomeric polyester, namely, poly(tetramethylene aspartate) (PTMA), was synthesized from D,L-aspartic acid and 1,4-butanediol by a melt-condensation technique. Polyester-metal complexes were synthesized by the reaction of PTMA with hydrated acetates of Mn(II), Co(II), Ni(II), Cu(II), Zn(II), Cd(II)
## Abstract **Summary:** A novel type of glycerolโderived, waterโsoluble polycarbonate with pendant, primary hydroxyl groups was prepared from 2โ(2โbenzyloxyethoxy)trimethylene carbonate (BETC). Ringโopening polymerization of BETC and 2,2โdimethyltrimethylene carbonate (DTC) gave narrow distributio