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Synthesis and Characterization of Novel Glycerol-Derived Polycarbonates with Pendant Hydroxyl Groups

✍ Scribed by Hujie Mei; Zhenlin Zhong; Feifu Long; Renxi Zhuo

Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
138 KB
Volume
27
Category
Article
ISSN
1022-1336

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✦ Synopsis

Abstract

Summary: A novel type of glycerol‐derived, water‐soluble polycarbonate with pendant, primary hydroxyl groups was prepared from 2‐(2‐benzyloxyethoxy)trimethylene carbonate (BETC). Ring‐opening polymerization of BETC and 2,2‐dimethyltrimethylene carbonate (DTC) gave narrow distribution of homopolymers or random copolymers with high molecular weights. The protecting benzyl groups were removed by catalyzed hydrogenation at atmosphere H~2~ pressure to give hydroxyl polycarbonates without observable changes on the polymer backbone and molecular weight distribution. The hydrophilicity of the copolymers increases with the increase in the hydrophilic glycerol‐derived carbonate content.

Synthesis of the glycerol‐derived polycarbonate.

magnified imageSynthesis of the glycerol‐derived polycarbonate.

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