Scheme 3. One-pot catalytic enantioselective synthesis of homoallylic alcohol 8 a and homoallylic amine 8 b. Scheme 4. Proposed reaction mechanism.
✦ LIBER ✦
One-Pot Three-Component Catalytic Enantioselective Synthesis of Homoallylboronates
✍ Scribed by Prof. Dr. Ismail Ibrahem; Palle Breistein; Prof. Dr. Armando Córdova
- Publisher
- John Wiley and Sons
- Year
- 2011
- Tongue
- English
- Weight
- 416 KB
- Volume
- 50
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
✦ Synopsis
Scheme 3. One-pot catalytic enantioselective synthesis of homoallylic alcohol 8 a and homoallylic amine 8 b. Scheme 4. Proposed reaction mechanism.
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## Abstract α‐Hydroxylamino phosphonates are synthesised in a one‐pot operation by three‐component coupling reactions of aldehydes, hydroxylamines and diethyl phosphite using 1‐butyl‐3‐methylimidazolium tetrafluoroborate ([bmim]BF~4~) or 1‐butyl‐3‐methylimidazolium hexafluorophosphate ([bmim]PF~6~)