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One-pot synthesis of precise polyisoxazoles by click polymerization: Copper (I)-catalyzed 1,3-dipolar cycloaddition of nitrile oxides with alkynes

โœ Scribed by Li, Yan; Cheng, Bin


Book ID
120381345
Publisher
John Wiley and Sons
Year
2013
Tongue
English
Weight
565 KB
Volume
51
Category
Article
ISSN
0887-624X

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## Abstract A safe, efficient, and improved procedure for the regioselective synthesis of 1โ€(2โ€hydroxyethyl)โ€1__H__โ€1,2,3โ€triazole derivatives under ambient conditions is described. Terminal alkynes reacted with oxiranes and NaN~3~ in the presence of a copper(I) catalyst, which is prepared by __in