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Peptidotriazoles on Solid Phase: [1,2,3]-Triazoles by Regiospecific Copper(I)-Catalyzed 1,3-Dipolar Cycloadditions of Terminal Alkynes to Azides

✍ Scribed by Tornøe, Christian W.; Christensen, Caspar; Meldal, Morten

Book ID: 115526019
Publisher: American Chemical Society
Year: 2002
Tongue: English
Weight: 119 KB
Volume: 67
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo011148j

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## Abstract A safe, efficient, and improved procedure for the regioselective synthesis of 1‐(2‐hydroxyethyl)‐1__H__‐1,2,3‐triazole derivatives under ambient conditions is described. Terminal alkynes reacted with oxiranes and NaN~3~ in the presence of a copper(I) catalyst, which is prepared by __in