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One-pot synthesis of cyclophane-type macrocycles using manganese(iii)-mediated oxidative radical cyclization

โœ Scribed by Ito, Yosuke; Tomiyasu, Yuichi; Kawanabe, Takahiro; Uemura, Keisuke; Ushimizu, Yuu; Nishino, Hiroshi


Book ID
118210278
Publisher
Royal Society of Chemistry
Year
2011
Tongue
English
Weight
444 KB
Volume
9
Category
Article
ISSN
1477-0520

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One-pot synthesis of azabicyclic peroxid
โœ Firoz Alam Chowdhury; Hiroshi Nishino; Kazu Kurosawa ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 242 KB

A simple azabicyclic peroxide synthesis was achieved by the manganese(III)-mediated oxidative formal [2+2+2] cycloaddition. A mixture of tetramic acid derivatives and alkenes was oxidized with manganese(HI) acetate under a dry air stream to give I-hydroxy-8-aza-2,3-dioxabicyclo[4.3.0]nonan-7-ones in