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One-pot synthesis of azabicyclic peroxides from tetramic acid derivatives by manganese(III)-mediated oxidative [2+2+2]cycloaddition

✍ Scribed by Firoz Alam Chowdhury; Hiroshi Nishino; Kazu Kurosawa

Book ID: 104260033
Publisher: Elsevier Science
Year: 1998
Tongue: French
Weight: 242 KB
Volume: 39
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(98)01765-1

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✦ Synopsis

A simple azabicyclic peroxide synthesis was achieved by the manganese(III)-mediated oxidative formal [2+2+2] cycloaddition. A mixture of tetramic acid derivatives and alkenes was oxidized with manganese(HI) acetate under a dry air stream to give I-hydroxy-8-aza-2,3-dioxabicyclo[4.3.0]nonan-7-ones in good to quantitative chemical yields.

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