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One-Pot Synthesis of Benzimidazoles from o-Nitroanilines under Microwaves via a Reductive Cyclization.

โœ Scribed by Mandar P. Surpur; Pankajkumar R. Singh; Sachin B. Patil; Shriniwas D. Samant


Publisher
John Wiley and Sons
Year
2007
Weight
18 KB
Volume
38
Category
Article
ISSN
0931-7597

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A Novel One-Pot Synthesis of 2-Aminoquinolines from Arylazidoketones by Cyclization under Vilsmeier Conditions. -The reaction of Vilsmeier reagent with 2-azidophenyl ketones is investigated. 1-(2-Azidophenyl)ethanone (I) yields a mixture of the aminoquinolines (III) and (IV). Unexpectedly, the anal