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ChemInform Abstract: A Novel One-Pot Synthesis of 2-Aminoquinolines from Arylazidoketones by Cyclization under Vilsmeier Conditions.

✍ Scribed by Ramiya R. Amaresh; Paramasivan T. Perumal

Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis

A Novel One-Pot Synthesis of 2-Aminoquinolines from Arylazidoketones by Cyclization under Vilsmeier Conditions.

-The reaction of Vilsmeier reagent with 2-azidophenyl ketones is investigated. 1-(2-Azidophenyl)ethanone (I) yields a mixture of the aminoquinolines (III) and (IV). Unexpectedly, the analogous propanones and butanones (V) give only unformylated products including the deaminated compounds (VII). -

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