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One-Pot Stereoselective Synthesis of Alkyl ( Z )-2-[4-Oxo-3-phenyl-2-(phenylimino)-1,3-thiazolan-5-yliden]acetates from Acetylenic Esters and N, N′ -Diphenylthiourea

✍ Scribed by Gonbari, Monireh Heshmati; Ramazani, Ali; Souldozi, Ali


Book ID
118055976
Publisher
Taylor and Francis Group
Year
2009
Tongue
English
Weight
114 KB
Volume
184
Category
Article
ISSN
1042-6507

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Potassium Thiocyanate-Promoted One-Pot S
✍ Issa Yavari; Mehdi Sirouspour; Sanaz Souri 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 German ⚖ 142 KB

## Abstract The reaction of aryl isocyanates and alkyl propiolates (=alkyl prop‐2‐ynoates) in the presence of potassium thiocyanate (KSCN) led to geometric isomers of alkyl 2‐(1,3‐diaryl‐2,5‐dioxoimidazolidin‐4‐ylidene)acetates in moderate‐to‐good yields.