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One-Pot Preparation of Arylalkynes by a Tandem Catalytic Iodination of Arenes and Palladium-Catalyzed Coupling of Iodoarenes with Terminal Alkynes.

โœ Scribed by Shun Wan; Sunewang R. Wang; Wenjun Lu

Publisher
John Wiley and Sons
Year
2006
Weight
22 KB
Volume
37
Category
Article
ISSN
0931-7597

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Abstract

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Development of a One-Pot Palladium-Catalyzed Hydrostannylation/Stille Coupling Protocol with Catalytic Amounts of Tin. ฮฑ-Trisubstituted alkynes are chosen as substrates in the title reaction utilizing a palladium catalyst and either Bu 3 SnH or (Bu 3 Sn) 2 O/PMHS as the hydride source to afford 1,3