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One-Pot Organocatalytic Domino Michael/α-Alkylation Reactions: Direct Catalytic Enantioselective Cyclopropanation and Cyclopentanation Reactions

✍ Scribed by Ismail Ibrahem; Gui-Ling Zhao; Ramon Rios; Jan Vesely; Henrik Sundén; Pawel Dziedzic; Armando Córdova

Publisher: John Wiley and Sons
Year: 2008
Tongue: English
Weight: 416 KB
Volume: 14
Category: Article
ISSN: 0947-6539
DOI: 10.1002/chem.200800442

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## Abstract The highly enantioselective organocatalytic domino aza‐Michael/aldol reaction is presented. The unprecedented, chiral amine‐catalyzed asymmetric domino reactions between 2‐aminobenzaldehydes and α,β‐unsaturated aldehydes proceed with excellent chemo‐ and enantioselectivity to give the c