ONE-POT CONVERSION OF CARBOXYLIC ACIDS TO ALDEHYDES BY TREATMENT OF ACYLOXY-9-BORABICYCLO[3,3,1]NONANES WITH LITHIUM tris (DIETHYLAMINO)ALUMINUM HYDRIDE

One-pot conversion of carboxylic acids t

One-pot conversion of carboxylic acids to aldehydes through treatment of acyloxy-9-borabicyclo[3.3.1]nonanes with lithium 9-boratabicyclo[3.3.1]nonane

✍ Jin Soon Cha; Jin Euog Kim; Se Yeon Oh; Jong Dae Kim 📂 Article 📅 1987 🏛 Elsevier Science 🌐 French ⚖ 245 KB

Carboxylic acids are readily reduced to the corresponding aldehydes in high yields by treatment of acyloxy-9-borabicycloC3.3.llnonanes with lithium 9-boratabicycloL3.3.l]nonane (Li 9-BBNH) at room temperature. Thexylchloroborane-methyl sulfide 2 and thexylbromoborane-methyl sulfide 3