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One-electron oxidation of organic substrates by oxochloride complex of rhenium(VI) in hydrochloric acid solutions

✍ Scribed by M. V. Koroleva; L. V. Borisova; A. K. Chibisov


Book ID
112366542
Publisher
Springer
Year
1987
Tongue
English
Weight
350 KB
Volume
23
Category
Article
ISSN
0040-5760

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The kinetics of oxidation of cis-[Cr III (phen) 2 (H 2 O) 2 ] 3+ (phen = 1,10-phenanthroline) by IO - 4 has been studied in aqueous acidic solutions. In the presence of a vast excess of [IO - 4 ], the reaction is first order in the chromium(III) complex concentration. The pseudo-firstorder rate cons